Contribution of the fluorescence spectroscopy to the determination of binary phase diagrams of mesomorphic mixtures. I. Investigation of a system-alkylcyanobiphenyl/phenyl-cyclohexanecarboxylate

نویسندگان

  • D. Baeyens-Volant
  • C. David
چکیده

2014 The study of the spectral distribution and intensity of the fluorescence of binary mesomorphic mixtures as a function of the temperature is presented as a convenient method for obtaining phase diagrams. For a mixture of a given composition, the fluorescence intensity measured in the frequency range of the monomer and of the excimer emission, shows two types of discontinuities at the phase transitions. Ratio IM/ID ranging from 0 to ~ can be obtained as a function of the composition, of the temperature, and of the nature of the phase. Monomer fluorescence (IM) is characteristic of the crystalline and of the SB phases while in the SA1, N and the I phases, excimer fluorescence (ID) is predominantly observed. The emission spectra can detect simultaneously the presence of molecular association, the degree of order and the molecular mobility of the phase involved. J. Physique 47 (1986) 2145-2152 DTCEMBRE 1986, Classification Physics Abstracts 61.30

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تاریخ انتشار 2016